Cristin-resultat-ID: 1193892
Sist endret: 22. januar 2015, 12:23
NVI-rapporteringsår: 2014
Resultat
Vitenskapelig oversiktsartikkel/review
2014

Recent approaches in mechanistic and kinetic studies of catalytic reactions using SSITKA technique

Bidragsytere:
  • Cristian Ledesma Rodriguez
  • Jia Yang
  • De Chen og
  • Anders Holmen

Tidsskrift

ACS Catalysis
ISSN 2155-5435
e-ISSN 2155-5435
NVI-nivå 2

Om resultatet

Vitenskapelig oversiktsartikkel/review
Publiseringsår: 2014
Volum: 4
Hefte: 12
Sider: 4527 - 4547

Importkilder

Scopus-ID: 2-s2.0-84915803472

Beskrivelse Beskrivelse

Tittel

Recent approaches in mechanistic and kinetic studies of catalytic reactions using SSITKA technique

Sammendrag

One of the most useful techniques to obtain valuable information on catalyzed heterogeneous reactions at, or near to, molecular level is the Steady-State Isotopic Transient Kinetic Analysis (SSITKA). Kinetic parameters of catalyst-surface reaction intermediates, such as concentration, site coverage, reactivity, and rate constants can be obtained and processed to provide valuable information about the reaction mechanism. This technique has been extensively tested in a wide range of different surface-catalyzed reactions, where the influence of different parameters on the intermediates has been studied (i.e., supports, active phases, particle size, addition of promoters). Progresses in the coupling of spectroscopic techniques and advanced modeling could greatly improve the understanding of the surface reaction mechanism and provide more reliable kinetic models. This review compiles the main goals achieved up to date in heterogeneous catalytic systems using SSITKA and analyzes the perspectives of this technique in the near future.

Bidragsytere

Cristian Ledesma Rodriguez

  • Tilknyttet:
    Forfatter
    ved Institutt for kjemisk prosessteknologi ved Norges teknisk-naturvitenskapelige universitet

Jia Yang

  • Tilknyttet:
    Forfatter
    ved Prosessteknologi ved SINTEF AS

De Chen

  • Tilknyttet:
    Forfatter
    ved Institutt for kjemisk prosessteknologi ved Norges teknisk-naturvitenskapelige universitet

Anders Holmen

  • Tilknyttet:
    Forfatter
    ved Institutt for kjemisk prosessteknologi ved Norges teknisk-naturvitenskapelige universitet
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